Solution and solid state studies of urea derivatives of. Anions play pivotal roles in biological, environmental and supramolecular sciences128. Sulfatetemplated 2d anionlayered supramolecular self. The ultimate goal of the studies on the basic chemical aspects of anion receptor design of functional phindependent systems is to target selective binding of anions of environmental significance. Supramolecular chemistry of selective anion recognition for anions of environmental relevance. Supramolecular chemistry of anions, wileyvch, new york 1997. Supramolecular chemistry of hostguest inclusion complexes chemistry. This thesis describes the supramolecular chemistry of different anion binding. Anion transport and supramolecular medicinal chemistry. Anion sensing by discrete molecular receptors relies on the fact that the recognition of a given anion by a receptor can induce a response, be it an optical color change or fluorescence, an electrochemical, or a solgel transition, that can be used to monitor the presence and in some cases the concentration of an anionic guest. The structures of the free macrocycle and its complex with h2p2o72. In supramolecular chemistry, the interest in anion recognition have grown in recent years, with the development of new sensors or chemosensors 7 10. Kristin bowmanjames, department of chemistry, university of kansas, 1251 wescoe hall drive, lawrence, kansas 660457582.
Recent developments and applications of the fundamental concepts have impacted a vast range of chemical disciplines, including diverse topics such as molecular machines, nanomedicine, supramolecular polymers, and lightresponsive systems. Supramolecular chemistry of helical foldamers at the solidliquid interface. In the context of supramolecular chemistry, the coordination concept as commonly applied to metal ions has been extended to polyatomic anionic species 1. The recognition ability was assessed by fluorescence titrations and electrospray ionization mass spectrometry. Whitea the interaction of tetratopic amidiniumcontaining receptors with terephthalate anions leads to porous. Syntheses of new covalent and supramolecular dendrimers and use for the electrochemical recognition of anions of biological interest, keio university, yokohama, japan, june 22.
Anion receptor chemistry chemical communications rsc. Special issue applications of supramolecular anion recognition. Anions play important roles in a wide range of natural and biological processes. May 28, 2020 a novel fluorescence chemosensor array composed of pyrenylboronic acidbased probes for multi anion detection has been developed. Apr 16, 2002 in addition, the subsequent anion recognition step must orient the macrocyclic ligand orthogonally to the cation to provide an interpenetrated geometry. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of anion complexes, sensing devices are presented and computational studies addressed. A synthetic supramolecular receptor for hydrosulfide anion. Polymerbased anion recognition and polymorph modification. Pdf anion recognition in supramolecular chemistry free online. Macromolecular, supramolecular and nanoscale msn chemistry. Pdf anion recognition in supramolecular chemistry free. The synthesis of molecularly imprinted polymers is an attractive method of creating recognition sites with memory to the target molecule in biological or aqueous media 11.
Herein, we present the synthesis and anion binding studies of a. Selective binding of choline by a phosphatecoordinationbased. Pdf, epub ebooks can be used on all reading devices immediate. A major focus of his research concerns the molecular recognition, sensing. Here, the crystal structure of 11 was bound to two nitrate anions in two distinct locations. Anion binding and new architectures in supramolecular chemistry. To optimize selective binding for hydrosulfide, we initially assumed the ideal receptor should feature hydrogen bond donors to target the anionic portion of hydrosulfide and a hydrogen bond acceptor or suitable pocket of electron density to. Supramolecular chemistry of selective anion recognition for. Supramolecular chemistry refers to the area of chemistry concerning chemical systems composed of a discrete number of molecules. Pdf calixnpyrroles as anion and ion pair complexants.
However, anion supramolecular chemistry has developed substantially beyond anion recognition, and now encompasses a diverse range of. Supramolecular chemistry second edition jonathan w. Supramolecular chemistry of anions, wileyvch, new york 1997 j. Cation and anion recognition of crown etherarmed metalloporphyrin. Supramolecular chemistry as applied to anion recognition.
Weitao gong state key laboratory of fine chemicals school of chemical engineering dalian university of technology p. It also serves as an excellent graduatelevel text for. Polymerbased anion recognition and polymorph modification graduate program. The most striking examples of hostguest complexes keeping. Phil gale is professor of supramolecular chemistry at the university of southampton. Building on the pioneering work in supramolecular chemistry from the last 20 years or so, this monograph addresses new and recent approaches to anion coordination chemistry. His research interests span a range of topics at the interface of supramolecular chemistry and inorganic chemistry, with a special regard to anion. Pdf calixnpyrroles as anion and ionpair complexants. To prepare this system, eight fluorescent polymeric gels g1g8 were synthesized. Supramolecular chemistry of selective anion recognition for anions of environmental relevance results from research conducted at the university of texas at austin lead principal investigator. Supramolecular chemistry of anions supramolecular chemistry. Recognition and sensing of anions in an aqueous solution is an important challenge in supramolecular chemistry.
Historical view on the development of anion coordination chemistry 45 bernard dietrich and mir wais hosseini, universite louis pasteur, strasbourg, france 45. Anion recognition as a supramolecular switch of cell. Anion recognition in supramolecular chemistry ebook, 2010. The supramolecular chemistry of selective anion recognition for anions of environmental relevance jonathan l. Since the start of this millennium, remarkable progress in the binding and sensing of anions has been taking place, driven in part by discoveries in the use of hydrogen bonding, as well as the previously under. Anion recognition as a supramolecular switch of cell internalization. Project 90301 the supramolecular chemistry of selective. Anion recognition in supramolecular chemistry books. Nov 06, 2019 supramolecular chemistry is an integral tool in the design and development of functional systems. Applications of supramolecular anion recognition nathalie busschaert, claudia caltagirone, wim van rossom, and philip a. Reported here is a twolayer gel construct that permits the onsite detection of the chloride anion by means of a handheld uvvis lamp and a smart phone app. Jan 01, 2006 this chapter discusses supramolecular chemistry of environmentally relevant anions. The project has developed into a highly interdisciplinary endeavor, encompassing coordination chemistry, computational chemistry, and, biochemistry. Anion templated selfassembly from anion complexes to.
Supramolecular chemistry of anionbinding receptors based. Pdf supramolecular chemistry and selfassembly special. Review anion recognition using dimetallic coordination complexes. Sessler covalent polymers containing discrete heterocyclic anion receptors philip a. Recent developments in the area of anion recognition and sensing have produced a variety of new selective receptors for anions. Supramolecular chemistry of environmentally relevant anions. Anion recognition in supramolecular chemistry anion recognition in supramolecular chemistry by philip a. Anion templated selfassembly from anion complexes to the. Major contributions of supramolecular chemistry have been devoted to recognition and sensing of anions. Impact of noncovalent interactions in determining key properties and behaviors. The stability constants for the binding of the receptor with tetrabutylammonium salts of hp2o73.
Special issue applications of supramolecular anion. Series title topics in heterocyclic chemistry series volume 24 copyright 2010 publisher springerverlag berlin. With development of more than 100 years, coordination chemistry has become a big family consisting of an everwidening range of branches, from classical werner transitionmetal complexes, clusters and organometallics, to hostguest complexes and supramolecular complexes alkali metal and alkalineearth metal complexes of macrocyclic ligands, crown ethers and cryptands. The study of the complexation of anions, from its beginnings in the late 1960s and 1970s, has moved on from being an area solely of academic interest to a fundamental pillar of supramolecular chemistry with applications in many areas. Supramolecular chemistry involving anions and anion pi interactions abstract. Anion recognition in supramolecular chemistry springerlink. Anion recognition in supramolecular chemistry editors. The strength of the forces responsible for spatial organization of the system range from weak intermolecular forces, electrostatic charge, or hydrogen bonding to strong covalent bonding, provided that the electronic coupling strength remains small relative to the.
Supramolecular chemistry of selective anion recognition. Polymer bound supramolecular assemblies for anion sensing. Steed department of chemistry, durham university, uk. Biologically important anions and reusable redox sensors, osaka university, osaka, japan, july 6, 2004. Supplemental experimental procedures, supplemental references, figures s1s92, and table s1s17. It is a simple matter to visualize this template in conjunction with other anions, cationic threads, and macrocyclic anion receptors, which is an ongoing topic of research in our laboratories. Binding of three different bacterial pdf inhibitors to peptide deformylase a.
Gale, chemistry, university of southampton, southampton so17 1bj, united kingdom dipartimento di scienze chimiche e geologiche, universitadegli studi di cagliari, s. Sigmahole interactions in anion recognition ora oxford. Conformational effect on the preferential binding of alkali metal cation with crown. Supramolecular chemistry of hostguest inclusion complexes grin. Over recent years we have seen the development of a plethora of anion sensors, anion responsive materials, organocatalytic processes involving anion complexation. Fumarate chains in spacefill format inside the channel formed by 12. However, anion supramolecular chemistry has developed substantially beyond anion recognition, and now encompasses a diverse range of disciplines. The molecular recognition of anions is a current, active and difficult area of supramolecular chemistry, considering the ubiquitious properties of anions15. Supramolecular chemistry of helical foldamers at the solid.
It would be a huge honor if you would join us in celebrating this rare occasion by submitting an article detailing your exciting research related to supramolecular anion binding and molecular recognition. Reflection of such actions and mechanisms of naturally occurred molecular machinery let to constantly develop the domain of supramolecular chemistry. Supramolecular chemistry 1 supramolecular chemistry an example of a supramolecular assembly. A 2,6diamidopyridinedipyrromethane macrocyclic receptor was prepared by a schiff base condensation reaction. Ion pairing is the most important driving force for anion complexation, but selectivity e. Supramolecular system composed of b 12 model complex and organic photosensitizer. Biomimetic macrocyclic receptors for carboxylate anion recognition based on clinked peptidocalix4arenes. Topics that are on the list for msn and related to this presentation. The pyrenylboronic acid derivatives showed fluorescence quenching or enhancement due to photoinduced electron transfer originating from anion binding. Supramolecular chemistry and selfassembly special feature. Stoddart editor, monographs in supramolecular chemistry, rsc.
A supramolecular photonic device porphyrins and tetrapyrrole macrocycles 2. Jan 15, 2000 correction for gale, supramolecular chemistry. Supramolecular chemistry involving anions and anionpi. Download in pdf, epub, and mobi format for read it on your kindle device, pc, phones or tablets. Anion recognition in supramolecular chemistry nasaads. In particular, the synthesis and investigation of various artificial systems based on this concept that are capable of potent and selective molecular recognition of anions in a face of their. In this first year of funding, progress has been made towards the stated project goal of generating useful sulfate extractants. To address this issue, we have characterised complex formation between human ubiquitin hub and four supramolecular anions. Of great interest is the design, syntheses and use of neutral. Sep 12, 2016 to approach this challenge, we reasoned that synthetic anion receptors could provide a viable platform to develop reversible hs. Frontiers fluorescence anion chemosensor array based on. The issue will consist of a series of invited papers contributed by scholars from all over the world.
The twovolume encyclopedia of supramolecular chemistry offers authoritative, centralized information on a rapidly expanding interdisciplinary field. These specific interactions are typical examples of molecular recognition. Review anion recognition using dimetallic coordination. General overview this chapter is intended to describe the principles, perspectives, and recent developments in the field of supramolecular chemistry, which has grown exponentially in the last few decades as indicated. Aletti, anna, anion templated selfassembly from anion complexes to the formation of supramolecular 2d networks, trinity college dublin.
Research in the supramolecular chemistry of anions is a newer project in the dunbar group. Covalent polymers containing discrete heterocyclic anion receptors. Anion binding properties for pyrophosphate derived from a 2,6. The recognition and complexation of anions has become undoubtedly one of the most important branches of modern supramolecular chemistry, as can easily be. Fluoride anions are an important target in supramolecular chemistry due to the. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of anion complexes, sensing devices are presented and computational studies addressed to aid with the. The publication of this work energized the scienti. Thus, the development of synthetic molecules designed to mimic the efficiency of the natural anion receptors is an intensively active area of research in supramolecular chemistry. Department of chemistry and biochemistry, university of notre dame, notre dame, in 46556, usa received 21 december 2005. The media could not be loaded, either because the server or network failed or because the format is not supported. For many years supramolecular chemistry was related mainly to the recognition and selective binding of cations. Anion recognition in supramolecular chemistry philip a. Bjoc chiral anion recognition using calix4arenebased ureido. Applications of supramolecular anion recognition chemical.
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